Deposición electroless de recubrimientos Ni-P y estudio de la infl uencia del contenido de fósforo en la resistencia a la corrosión
DOI:
https://doi.org/10.17533/udea.redin.18834Palabras clave:
electroless Ni-P, acero, resistencia a la corrosiónResumen
Se prepararon recubrimientos Ni-P por tecnología autocatalítica (electroless) y se estudió la morfología y capacidad anticorrosiva en función del contenido de fósforo. Con el fi n de obtener recubrimientos de diferente concentración de fósforo se operaron baños con dos grados de acidez, pH básico y pH ácido. El poder protector de los recubrimientos aumentó con la concentración de fósforo; esta evaluación se realizó mediante medidas de polarización. Morfológicamente, los recubrimientos obtenidos en medio ácido (con un 7,9% P), presentaron un aspecto liso y los recubrimientos obtenidos en medio básico (2,6% P) son nodulares. Igualmente, se midió la velocidad de deposición y el espesor de capa.
Descargas
Citas
R. Taheri. I. Oguocha, S. Yannacopoulos. “The tribological characteristics of electroless Ni-P coatings”. Wear. Vol. 249. 2001. pp. 389-339. DOI: https://doi.org/10.1016/S0043-1648(01)00539-7
J. Winowlin. “A study on the influence of process parameters on efficiency and cristallinity of electroless Ni-P deposits”. Journal of Materials Processing Technology. Vol. 169. 2005. pp. 308-31. DOI: https://doi.org/10.1016/j.jmatprotec.2005.03.010
Z. Aixiang. “Electroless Ni-P coating of cenospheres using silver nitrate activator plating by nonisothermal method”. Surface and coatings technology. Vol. 197. 2005. pp. 142-147. DOI: https://doi.org/10.1016/j.surfcoat.2005.01.009
J. Balaraju. “Electroless deposition of Ni-Cu-P, Ni-W-P & Ni-W-Cu-P alloys”. Surface and coatings technology. Vol. 195. 2005. pp. 154-161. DOI: https://doi.org/10.1016/j.surfcoat.2004.07.068
J. Balaraju. “Studies on electroless Ni-W-P and Ni-W-Cu-P alloy coatings using chloride bath”. Surface and Coatings Technology. Vol. 197. 2005. pp. 161-167.
B. Chen. “Effects of surfactants in an electroless Niplating bath on the properties of Ni-P alloy deposits”. Industrial engineering chemistry research. Vol. 41. 2002. pp. 2668-2678. DOI: https://doi.org/10.1021/ie0105831
Y. Gao. “Corrosion resistance of electrolessly deposited Ni-P & Ni-W-P alloyds with various structures”. Material science and engineering A. Vol. 381. 2004. pp. 98-103. DOI: https://doi.org/10.1016/j.msea.2004.04.077
M. Ger. “A novel process of electroless Ni-P plating by nonisothermal method”. Material chemistry and physics. Vol. 89. 2005. pp. 383-389. DOI: https://doi.org/10.1016/j.matchemphys.2004.09.018
S. Shibli. G. Jabeera. R. Anupama. “Incorporation of nano zinc oxide for improvement of electroless nickel plating”. Applied Surface Science. Vol. 253. 2006. pp. 1644-1648.
S. Shibli. G. Jabeera. R. Anupama. “Development of ZnO incorporated composite Ni–ZnO–P alloy coating”. Surface and Coatings Technology. Vol. 200. 2006. pp. 3903-3906. DOI: https://doi.org/10.1016/j.surfcoat.2004.10.017
Ch. Gu. “Electroless Ni-P plating on AZ91D magnesium alloy from a sulfate solution”. Journal of alloyds and composites. Vol. 391. 2005. pp. 104-109. DOI: https://doi.org/10.1016/j.jallcom.2004.07.083
J. Balaraju. T. Sankara. T. Narayanan. S. Seshadri. “Structure and phase transformation behaviour of elec-troless Ni–P composite coatings”. Materials Research Bulletin. Vol. 41. 2006. pp. 847-860.
J. Balaraju. T. Sankara. T. Narayanan. S. Seshadri. “Effect of accelerators and stabilizers on the formation and characteristics of electroless Ni–P deposits”. Materials Chemistry and Physics. Vol. 99. 2006. pp. 117-126.
E. Touhami. E. Chassaing. M. Cherkaoui. “Kinetics of the autocatalytic deposition of Ni-P alloys in ammoniacal solutions”. Electrochimica Acta. Vol. 43. 1998. pp. 1721-1728 DOI: https://doi.org/10.1016/S0013-4686(97)00322-8
E. Touhami. E. Chassaing. M. Cherkaoui. “Modelisation of Ni–P electroless deposition in ammoniacal solutions”. Electrochimica Acta. Vol. 48. 2003. pp. 3651-3658.
Q. Zhao. Y. Liu. “Modification of stainless steel surfaces by electroless Ni-P & small amount of PTFE to minimize bacterial adhesion”. Journal of Food Engineering. Vol. 72. 2006. pp. 266-272. DOI: https://doi.org/10.1016/j.jfoodeng.2004.12.006
M. Ger. “Transient phenomena of the codeposition of PTFE with electroless Ni-P coating at the early stage”. Materials chemistry and physics. Vol. 87. 2004. pp. 102-108. DOI: https://doi.org/10.1016/j.matchemphys.2004.05.004
S. Narayanan. I. Baskaran. K. Krishnaveni. S. Parthiban. “Deposition of electroless Ni-P graded coatings & evaluation of their corrosion resistance”. Surface and Coatings Technology. Vol. 200. 2006. pp. 3438-3445. DOI: https://doi.org/10.1016/j.surfcoat.2004.10.014
S. Rossi. F. Chini. G. Straffelini. P. Bonora. R. Moschini. A. Stampali. “Corrosion protection properties of electroless Nickel/PTFE, Phosphate/MoS2 and Bronze/PTFE coatings applied to improve the wear resistance of carbon steel”. Surface and Coatings Technology. Vol. 173. 2003. pp. 235-245. DOI: https://doi.org/10.1016/S0257-8972(03)00662-5
P. TAO and others. “XPS & AES investigation of nanometer composite coatings of Ni-P-ZnX on steel surface (ZnX= ZnSnO3, Zn(PO4)2 y ZnSiO3))”. Applied surface science. Vol. 181. 2001. pp. 191-196.
B. Oraon. G. Majumdar. B. Ghosh. “Application of response surface method for predicting electroless nickel plating”. Materials & Design. Vol. 27. 2006. pp. 1035-1044. DOI: https://doi.org/10.1016/j.matdes.2005.01.025
S. Shiue. “Effect of the coating thickness and rough-ness on the mechanical strength and thermally induced stress voids in nickel-coated optical fibers prepared by electroless plating method”. Thin Solid Films. Vol. 485. 2005. pp. 169-175.
E. Touhami. E. Chassaing. M. Cherkaoui. “Effect of accelerators and stabilizers on the formation and characteristics of electroless Ni–P deposits”. Materials Chemistry and Physics. Vol. 99. 2006. pp. 117-126.
B. Oraon. G. Majumdar. B. Ghosh. “Parametric optimization and prediction of electroless Ni–B deposition”. Materials & Design. Vol. 28. 2007. pp. 2138-2147 DOI: https://doi.org/10.1016/j.matdes.2006.05.017
E. Touhami. E. Chassaing. M. Cherkaoui. “Modelisation of Ni–P electroless deposition in ammoniacal solutions”. Electrochimica Acta. Vol. 48. 2003. pp. 3651-3658. DOI: https://doi.org/10.1016/S0013-4686(03)00486-9
T. Burchardt. “The effect of deposition temperature on the catalytic activity of Ni–P alloys toward the hydrogen reaction”. International Journal of Hydrogen Energy. Vol. 27. 2002. pp. 323-328. DOI: https://doi.org/10.1016/S0360-3199(01)00111-2
X. Haowen. Z. Bangwei. “Effects of preparation technology on the structure and amorphous forming region for electroless Ni–P alloys”. Journal of Materials Processing Technology. Vol. 124. 2002. pp. 8-13. DOI: https://doi.org/10.1016/S0924-0136(01)01021-4
H. Ashassi-sorkhabi. S. Rafi zadeh, “Effect of coating time and heat treatment on structures and corrosion characteristics of electroless Ni–P alloy deposits”. Surface and Coatings Technology. Vol. 176. 2004. pp. 318-32. DOI: https://doi.org/10.1016/S0257-8972(03)00746-1
J. Balaraju. D. Kalavati. R. Rajam. “Infl uence of particle size on the microstructure, hardness and corrosion resistance of electroless Ni–P–Al2O3 composite coatings”. Surface and Coatings Technology. Vol. 200. 2006. pp. 3933-3941. DOI: https://doi.org/10.1016/j.surfcoat.2005.03.007
H. Ashassi-Sorkhabi. M. Dolati. N. Parvini-Ahmadi. J. Manzoori. “Electroless deposition of Ni–Cu–P alloy and study of the influences of some parameters on the properties of deposits”. Applied Surface Science. Vol. 185. 2002. pp. 155-160. DOI: https://doi.org/10.1016/S0169-4332(01)00464-0
J. Balaraju. T. Sankara. T. Narayanan. S. Seshadri. “Structure and phase transformation behaviour of electroless Ni–P composite coatings”. Materials Research Bulletin. Vol. 41. 2006. pp. 847-860. DOI: https://doi.org/10.1016/j.materresbull.2005.09.024
P Tao and others. “XPS & AES investigation of nanometer composite coatings of NI-P-ZnX on steel surface (ZnX= ZnSnO3, Zn(PO4)2 y ZnSiO3))”. Applied surface science. Vol. 181. 2001. pp. 191-196. DOI: https://doi.org/10.1016/S0169-4332(01)00343-9
H. Xu. “Synthesis and properties of electroless Ni-P-Nanometer diamond composite coatings”. Surface and coatings technology. Vol. 191. 2005. pp. 161-165. DOI: https://doi.org/10.1016/j.surfcoat.2004.03.045
Z. Yang. “Preparation and properties of Ni/P/single walled carbon nanotubes composite coatings by means of electro-less plating”. Thin solid films. Vol. 466. 2004. pp. 86-91. DOI: https://doi.org/10.1016/j.tsf.2004.02.016
Ch. Gu and others. “High corrosion-resistant Ni-P/Ni/Ni-P multilayer coatings on steel”. Surface and coatings technology. Vol. 197. 2005. pp. 61-67. DOI: https://doi.org/10.1016/j.surfcoat.2004.11.004
N. Shrestha. D. Hamal. T. Saji. “Composite plating of Ni–P–Al2O3 in two steps and its anti-wear performance”. Surface and Coatings Technology. Vol. 183. 2004. pp. 247-253.
J. Li. “Studies of the porosity in electroless Ni deposits on magnesium alloy”. Applied Surface Science. Vol. 252. 2006. pp. 2839-2846.
S. Shibli. B. Jabeera. R. Anupama. “Incorporation of nano zinc oxide for improvement of electroless nickel plating”. Applied Surface Science. Vol. 253. 2006. pp. 1644-1648. DOI: https://doi.org/10.1016/j.apsusc.2006.02.063
T. Khoperia. “Electroless deposition in nanotechnology and ULSI”. Microelectronic Engineering. Vol. 69. 2003. pp. 384-390. DOI: https://doi.org/10.1016/S0167-9317(03)00325-3
P. Sampath. P. Kesavan. “Studies on crystallization of electroless Ni-P deposits”. Journal of Materials Processing Technology. Vol. 56. 1996. pp. 511-52. DOI: https://doi.org/10.1016/0924-0136(96)85110-7
N. Shrestha. D. Hamal. J. Saji. “Composite plating of Ni–P–Al2O3 in two steps and its anti-wear performance”. Surface and Coatings Technology. Vol. 183. 2004. pp. 247-253.
G. Straffelini. D. Colombo. A. Molinari. “Surface durability of electroless Ni–P composite deposits”. Wear. Vol. 236. 1999. pp. 179-188. DOI: https://doi.org/10.1016/S0043-1648(99)00273-2
D. Singh. R. Ghosh. “Electroless nickel–phosphorus coatings to protect steel reinforcement bars from chloride induced corrosion”. Surface and Coatings Technology. Vol. 201. 2006. pp. 90-101. DOI: https://doi.org/10.1016/j.surfcoat.2005.10.045
Z. Liu. “Electroless plating of copper through successive pretreatment with silane and colloidal silver”. Colloids and Surfaces A: Physicochemical and Engineering Aspects. Vol. 257-258. 2005. pp. 283-28. DOI: https://doi.org/10.1016/j.colsurfa.2004.10.036
N. Shrestha. D. Hamal. J. Saji. “Composite plating of Ni–P–Al2O3 in two steps and its anti-wear performance”. Surface and Coatings Technology. Vol. 183. 2004. pp. 247-254. DOI: https://doi.org/10.1016/j.surfcoat.2003.08.085
S. Shiue. Ch. Yang. R. Chu. Tsong-Jen. “Effect of the coating thickness and roughness on the mechanical strength and thermally induced stress voids in nickel-coated optical fibers prepared by electroless plating method”. Thin Solid Films. Vol. 485. 2005. pp. 169-175. DOI: https://doi.org/10.1016/j.tsf.2005.04.024
H. Ashassi-Sorkhabi. A. Mirmohseni. H. Harrafi , “Evaluation of initial deposition rate of electroless Ni–P layers by QCM method”. Electrochimica Acta. Vol. 50. 2005. pp. 5526-5532. DOI: https://doi.org/10.1016/j.electacta.2005.03.056
H. Keping. J. Li. “Stabilization effect of electroless nickel plating by thiourea”. Metal Finishing. Vol. 95. 1997. pp. 73-75. DOI: https://doi.org/10.1016/S0026-0576(97)81818-1
I. Baskaran. T.S.N. Sankara Narayanan. A. Stephen. “Effect of accelerators and stabilizers on the formation and characteristics of electroless Ni–P deposits” Materials Chemistry and Physics. Vol. 99. 2006. pp. 117-126. DOI: https://doi.org/10.1016/j.matchemphys.2005.10.001
J. Li. Y. Tian. Z. Huang. X. Zhang. “Studies of the porosity in electroless nickel deposits on magnesium alloy”. Applied Surface Science. Vol. 252. 2006. pp. 2839-2846. DOI: https://doi.org/10.1016/j.apsusc.2005.04.028
J. Balaraju. J. Millath. K. Rajam. “Studies on autocatalytic deposition of ternary Ni–W–P alloys using nickel sulphamate bath”. Surface and Coatings Technology. Vol. 201. 2006. pp. 507-512. DOI: https://doi.org/10.1016/j.surfcoat.2005.11.131
A. Grosjean. A. Rezrazi. P. Berçot, “Some morphological characteristics of the incorporation of silicon carbide (SiC) particles into electroless nickel deposits”. Surface and Coatings Technology. Vol. 130. 2000. pp. 252-256. DOI: https://doi.org/10.1016/S0257-8972(00)00714-3
G. Jiaqiang. W. Yating. L. Lei. S. Bin. H. Wenbin. “Crystallization temperature of amorphous electroless nickel–phosphorus alloys”. Materials Letters. Vol. 59. 2005. pp. 1665-1669. DOI: https://doi.org/10.1016/j.matlet.2004.11.064
Descargas
Publicado
Cómo citar
Número
Sección
Licencia
Los artículos disponibles en la Revista Facultad de Ingeniería, Universidad de Antioquia están bajo la licencia Creative Commons Attribution BY-NC-SA 4.0.
Eres libre de:
Compartir — copiar y redistribuir el material en cualquier medio o formato
Adaptar : remezclar, transformar y construir sobre el material.
Bajo los siguientes términos:
Reconocimiento : debe otorgar el crédito correspondiente , proporcionar un enlace a la licencia e indicar si se realizaron cambios . Puede hacerlo de cualquier manera razonable, pero no de ninguna manera que sugiera que el licenciante lo respalda a usted o su uso.
No comercial : no puede utilizar el material con fines comerciales .
Compartir igual : si remezcla, transforma o construye a partir del material, debe distribuir sus contribuciones bajo la misma licencia que el original.
El material publicado por la revista puede ser distribuido, copiado y exhibido por terceros si se dan los respectivos créditos a la revista, sin ningún costo. No se puede obtener ningún beneficio comercial y las obras derivadas tienen que estar bajo los mismos términos de licencia que el trabajo original.