Nuevos derivados imino-quitosano: desde la química verde a la remoción de metales pesados en aguas
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https://doi.org/10.17533/udea.redin.n89a05Palabras clave:
biopolímeros, quitosano, química verde, grado de desacetilación, tratamiento de aguasResumen
Se sintetizaron tres nuevos derivados imino-quitosano por condensación entre los grupos amino terminales del quitosano y 4-bromometil-2-hidroxibenzaldehido A1, Ácido 4-formil-2-hidroxibenzoico A2, y (E)-6-((2-(piridin-2-il)hidrazono)metil)picolinaldehido A3. Es de destacar en este trabajo que las reacciones fueron llevadas a cabo en medio acuoso empleando condiciones suaves de reacción (70°C). Los nuevos compuestos fueron caracterizados por RMN-1H, FT-IR, análisis elemental, análisis termo gravimétrico (TGA) y calorimetría diferencial de barrido (DSC). Se realizó un estudio de solubilidad a diferentes valores de pH para los tres compuestos, estableciendo comportamientos diferentes a los obtenidos con el quitosano extraído. Por último, mediante medidas de absorción atómica, se investigó la capacidad de los derivados imino-quitosano en la remoción de iones de metales pesados en agua, tales como Pb(II) y Hg(II), el cual mostró un alto porcentaje de remoción a pH básicos pero uno a pH por debajo de 5. Adicionalmente la naturaleza del sustituyente determinó la solubilidad de los aductos resultantes ampliando así las potenciales aplicaciones de estos derivados de quitosano.
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