Esterification of levulinic acid via catalytic and photocatalytic processes using fluorinated titanium dioxide materials

Keywords: Catalysis, photocatalysis, levulinic acid, esterification, TiO2-F

Abstract

This study evaluated the synthesis, characterization, and activity of fluorinated titanium dioxide materials (TiO2-F 1% and TiO2-F 5%) in-situ modified by the sol-gel method in the esterification reaction of levulinic acid conducted by catalytic and photocatalytic processes. The physicochemical properties of the materials were determined by X-ray diffraction, UV–Vis diffuse reflectance spectroscopy, thermal analysis, and pyridine adsorption. It was found that the inclusion of fluoride anion causes a decrease in the levulinic acid conversion by photocatalytic reaction; however, in the catalytic activation, a slight increase in the conversion using the fluoride materials was observed. Finally, the reaction in the presence of halogenated solvents (CCl4) by photolysis reaction favors a conversion of 100% in 1h.

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Author Biographies

Claudia Patricia Castañeda Martínez, Universidad Pedagógica y Tecnológica de Colombia

Professor, Chemical Sciences School

José Jobanny Martínez Zambrano, Universidad Pedagógica y Tecnológica de Colombia

Professor, Chemical Sciences School

Andrés Camilo Mesa, Universidad Pedagógica y Tecnológica de Colombia

Student, Chemical Sciences School

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Published
2021-05-24
How to Cite
Castañeda Martínez C. P., Martínez Zambrano J. J., & Mesa A. C. (2021). Esterification of levulinic acid via catalytic and photocatalytic processes using fluorinated titanium dioxide materials. Revista Facultad De Ingeniería Universidad De Antioquia. https://doi.org/10.17533/udea.redin.20210531
Section
Research paper