Depósito electroquímico de recubrimientos compuestos de Ni-SiC y evaluación de su comportamiento anticorrosivo
DOI:
https://doi.org/10.17533/udea.redin.15926Keywords:
Níquel, SiC, Recubrimientos compuestos, electrodeposición, corrosión-erosiónAbstract
En el presente estudio se reporta la obtención de recubrimientos de Ni puro y compuestos de Ni con partículas nanométricas de SiC. Los recubrimientos fueron depositados sobre sustratos de acero al carbono AISI-SAE 1016 mediante polarización lineal sobre un electrodo de disco rotatorio, variando la velocidad de rotación y el contenido de partículas de SiC en el baño. Los recubrimientos fueron obtenidos a partir de una solución tipo Watts clásica, en la cual se adicionaron nanopartículas de SiC. Las propiedades anticorrosivas de los recubrimientos se estudiaron mediante técnicas electroquímicas y ensayos de corrosión-erosión. La microestructura de los recubrimientos se estudió mediante microscopía óptica. Se encontró que a medida que aumenta la cantidad de partículas en los recubrimientos aumenta la nobleza y la resistencia a la corrosión-erosión de los mismos. De la misma manera las propiedades mecánicas de los recubrimientos mejoran notablemente con el incremento de la cantidad de partícula en el depósito y con el aumento de la velocidad de agitación del baño durante la electrodeposición.Downloads
References
P. L. Mangonon. Ciencia de materiales: selección y diseño. Ed. Prentice Hall. México. 2001. pp. 592.
P. Molera Solá. Metales Resistentes a la corrosión. Ed. Marcombo. Barcelona. 1990. pp. 98-99.
F. Bratu, L. Benea, J. P. Celis. “Tribocorrosion behavior of Ni–SiC composite coatings under lubricated conditions”. Surface & Coatings Technology. Vol. 201. 2007. pp. 6940-694.
I. García, J. Fransaer, J. Cellis. “Electrodeposition and sliding wear resistance of nickel composite coatings containing micron and submicron SiC particles”. Surface and Coatings Technology. Vol. 148. 2001. pp. 171-178.
M. Vaezi, S. Sadrnezhaad, L. Nikzad. “Electrodeposition of Ni-SiC nano-composite coatings and evaluation of wear and corrosion resistance and electroplating characteristics”. Colloids and Surfaces A: Physicochem. Eng. Aspects. Vol. 315 .2008. pp. 176-182.
A. Abdel Aal, S. M. El-Sheikh, Y. M. Z Ahmed. “Electrodeposited composite coating of Ni W P with nano sized rod and spherical shaped SiC particles”. Materials Research Bulletin. Vol. 44. 2009. pp. 151-159.
M. Srivastava, V. K. Grips, K. S. Rajam. “Influence of SiC, Si3N4 and Al2O3 particles on the structure and properties of electrodeposited Ni”. Materials Letters. Vol. 62. 2008. pp. 3487-3489.
A. Abdel Aal, H. A. Gobran, F. Muecklich. “Electrodeposition of Ni-RuAl composite coating on steel surface”. Journal of Alloys and Compounds. Vol. 473. 2009. pp. 250-254.
S. T. Aruna, V.K. Grips, K.S. Rajaml. “Ni-based electrodeposited composite coating exhibiting improved microhardness, corrosion and wear resistance properties”. Journal of Alloys and Compounds. Vol. 468. 2009. pp. 546-552.
Z. Huang, D. Xiong. “MoS2 coated with Al2O3 for Ni MoS2/Al2O3 composite coatings by pulse electrodeposition”. Surface and Coatings & Technology. Vol. 202. 2008. pp. 3208-3214.
L. Shi, C. Sun, W. Liu. ”Electrodeposited nickel cobalt composite coating containing MoS2”. Applied Surface Science. Vol. 254. 2008. pp. 6880-6885.
P. Gyftou, E. A. Pavlatou, N. Spyrellis. “Effect of pulse electrodeposition parameters on the properties of Ni/ nano SiC composites”. Applied Surface Science. Vol. 254. 2008. pp. 5910-5916.
X. Cui, W. Wei, H. Liu, W. Chen. “Electrochemical study of codeposition of Al particle Nanocrystalline Ni/Cu composite coatings”. Electrochimica Acta. Vol. 54. 2008. pp. 415-420.
E. Pompei, L. Magagnin, N. Lecis, P.L. Cavallotti. “Electrodeposition of nickel-BN composite coatings”. Electrochimica Acta. Vol. 54. 2009. pp. 2571-2574.
E. García-Lecina, I. García-Urrutia, J.A. Díez, M. Salvo, F. Smeacetto, G. Gautier, R. Seddon, R. Martin. “Electrochemical preparation and characterization of Ni/SiC compositionally graded multilayered coatings”. Electrochimica Acta. Vol. 54. 2009. pp. 2556-2562.
Y. Yingwu, Y. Suwei, Z. Lu. “Electrochemical impedance spectroscopy and corrosion behavior Al2O3 Ni nanocomposite coatings”. Electrochimica Acta. Vol. 53. 2008. pp. 4557-4563.
F. Hu, K. Chan. “Deposition behavior and morphology of Ni-SiC electro- composites under triangular waveform”. Applied Surface Science. Vol. 243. 2004. pp. 251-258.
N. Zhao, C. Fa-he, W. Wei. ”Electrodeposition of Ni- SiC nanocomposite film”. Transactions of Nonferrous Metals Society of China. Vol. 17. 2006. pp. 9-15.
Y. Yingwu, Y. Suwei, Z. Lu. “Corrosion behavior of Ni-W/SiC nanocomposite coating in NaCl solution”. Surface Review and Letters. Vol. 13. 2006. pp. 489-494.
W. Hongzhi, Y. Suwei, M. Sowjun. ”Electrochemical preparation and characterization of Ni/SiC gradient deposit”. Materials Processing Technology.Vol. 145. 2003. pp. 299-302.
M. Srivastava, V. K. Grips, K. S. Rajam. “Electrochemical deposition and tribological behaviour of Ni and Ni–Co metal matrix composites with SiC nano-particles”. Applied Surface Science. Vol. 253. 2007. pp. 3814–3824.
I. Brahim. “Black nickel electrodeposition from a modified Watts bath”. Journal of Applied Electrochemistry. Vol. 36. 2006. pp. 295-301.
A. F. Zimmerman, D. G. Clark, K. T. Aust, U. Erb. “Pulse electrodeposition of Ni–SiC nanocomposite”. Materials Letters. Vol. 52. 2002. pp. 85–90.
C. Malfatti, J. Ferreira, C. Santos, B. Souza, E. Fallavena, S.Vaillant, J. Bonino. “NiP/SiC composite coatings: the effects of particles on the electrochemical behavior”. Corrosion Science. Vol.
2004. pp. 567- 580.
Y. Zhou. Y. Ding. “Oxidation resistance of co deposited Ni SiC nanocomposite coating”. Transactions of Nonferrous Metals Society of China. Vol. 17. 2007. pp. 925 928.
L. Benea, V. Iordache, F. Wenger, P. Ponthiaux. “Nanostructured SiC-Ni composite coatings obtained by electrodeposition a tribocorrosion study”. Fascicle IX Metallurgy and Materials Science. Vol. 1. 2005. pp. 1453-1457.
L. Benea, P. L. Bonora, A. Borello, S. Martelli, F. Wenger, P. Ponthiaux, J. Galland. “Preparation and investigation of nanostructured SiC-Nickel layers by electrodeposition”. State Ionics. Vol. 151. 2002. pp. 89-95.
I. Epelboin, M. Joussellin, R. Wiart. “Impedance measurements for nickel deposition in sulfate and chloride electrolytes”. J. Electroanal. Chem. Vol. 119. 1981. pp. 61-71.
A. Magdy, M. Ibrahim. “Black nickel electrodeposition from a modified Watts bath”. J. Appl. Electrochem. Vol. 36. 2006. pp. 295–301.
E. Chassaing, M. Joussellin, R. Wiart. “The Kinetics of Nickel Electrodeposition Inhibition By Adsorbed Hydrogen And Anions”. J. Electroanal. Chem. Vol. 157. 1983. pp.75-88.
S. W. Watson, R. P. Waiters. “The Effect of Chromium Particles on Nickel Electrodeposition”. J. Electrochem. Soc. Vol. 138. 1991. pp. 3633-3637.
S. W. Watson. “Electrochemical Study of SiC Particle Occlusion during Nickel Electrodeposition”. J. Electrochem. Soc. Vol. 140. 1993. pp. 2235-2238.
L. Torres. Obtención y Caracterización de Recubri¬mientos Compuestos de Nanopartículas de Carburo de Silicio (SiC) y Diamante en una Matriz de Níquel. Trabajo de investigación de Maestría en Ingeniería, Universidad de Antioquia. Medellín. 2007. pp. 69-98.
C. C. Hu, C. Y. Lin, T. C. Wen. “Textural and electrochemical properties of Watts nickel-deposited titanium electrodes”. Mater. Chem. Phys. Vol. 44. 1996. pp. 233-238.
E. A. Pavlatou, M. Stroumbouli, P. Gyftou, N. Spyrellis. “Hardening effect induced by incorporation of SiC particles in nickel electrodeposits”. J. Appl. Electrochem. Vol. 36. 2006. pp. 385-394.
F. Denise, H. Leidheiser Jr. “An X-Ray Study of the Effect of Organic Compounds on the Crystal Growth of Nickel during Electrodeposition”. J. Electrochem. Soc. Vol. 100. 1953. pp. 490-495.
C. S. Lin, K. C. Huang. “Codeposition and microstructure of nickel–SiC composite coating electrodeposited from sulphamate bath”. J. Appl. Electrochem. Vol. 34. 2004. pp. 1013–1019.
J. M. Guilemany, J. Fernández , J. Delgado , A.V. Benedetti, F. Climent. “Effects of thickness coating on the electrochemical behaviour of thermal spray Cr C –NiCr coatings”. Surface and Coatings Technology. Vol. 153. 2002. pp. 107-113.
D. Chidambarama, C. R. Claytona, M. R. Dorfman. “Evaluation of the electrochemical behavior of HVOF-sprayed alloy coatings – II”. Surface & Coatings Technology. Vol. 192. 2005. pp. 278-283.
P. H. Suegamaa, C. S. Fugivara, A. V. Benedetti, J. M. Guilemany, J. Fernández, J. Delgado. “The influence of gun transverse speed on electrochemical behaviour of thermally sprayed Cr3C2–NiCr coatings in 0.5 M H2SO4 solution”. Electrochimica Acta. Vol. 49. 2004. pp. 627-634.
L. Shi, C. Sun, P. Gao, F. Zhou, W. Liu. “Mechanical properties and wear and corrosion resistance of electrodeposited Ni–Co/SiC nanocomposite coating”. Appl. Surf. Sci. Vol. 252. 2006. pp. 3591
L. Y. Wang, J. P. Tu, W. X. Chen, Y. C. Wang, X. K. Liu, C. Olk, D. H. Cheng, X. B. Zhang, “Friction and wear behavior of electroless Ni-based CNT composite coatings”. Wear. Vol. 254 2003. pp. 1289.
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