Estudio cinético de la fotooxidación del 4-clorofenol con oxígeno singulete generado por la tetra(4-carboxifenil)porfirina adsorbida sobre dióxido de silicio
DOI:
https://doi.org/10.17533/udea.redin.12461Palabras clave:
oxígeno singulete, porfirina, silica, fotooxidación, 4-clorofenol, cinética Langmuir-HinshelwoodResumen
La fotooxidación del 4-clorofenol con oxígeno singulete fue estudiada en solución acuosa. Las reacciones fueron realizadas, en un sistema heterogéneo, usando la tetra(4-carboxifenil)porfirina adsorbida sobre dióxido de silicio (TcPPH/SiO2) como sensibilizador. La fotogeneración de oxígeno singulete producido por la TcPPH/SiO2 con luz visible fue analizada por resonancia paramagnética electrónica (EPR) usando la técnica de spin trapping. La hidroquinona y benzoquinona fueron identificados por HPLC como los productos principales de la reacción de fotooxidación. La fotooxidación catalítica del 4-clorofenol sigue una cinética global de Langmuir-Hinshelwood.
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