Estudio cinético de la fotooxidación del 4-clorofenol con oxígeno singulete generado por la tetra(4-carboxifenil)porfirina adsorbida sobre dióxido de silicio

  • Carlos Dias-Uribe Universidad Industrial de Santander, Universidad del Atlántico.
  • Martha Daza Universidad Industrial de Santander
  • Edgar Páez Mozo Universidad Industrial de Santander
  • Fernando Martínez Universidad Industrial de Santander,

Abstract

La fotooxidación del 4-clorofenol con oxígeno singulete fue estudiada en solución acuosa. Las reacciones fueron realizadas, en un sistema heterogéneo, usando la tetra(4-carboxifenil)porfirina adsorbida sobre dióxido de silicio (TcPPH/SiO2) como sensibilizador. La fotogeneración de oxígeno singulete producido por la TcPPH/SiO2 con luz visible fue analizada por resonancia paramagnética electrónica (EPR) usando la técnica de spin trapping. La hidroquinona y benzoquinona fueron identificados por HPLC como los productos principales de la reacción de fotooxidación. La fotooxidación catalítica del 4-clorofenol sigue una cinética global de Langmuir-Hinshelwood.

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Published
2012-07-30
How to Cite
Dias-Uribe C., Daza M., Páez Mozo E., & Martínez F. (2012). Estudio cinético de la fotooxidación del 4-clorofenol con oxígeno singulete generado por la tetra(4-carboxifenil)porfirina adsorbida sobre dióxido de silicio. Revista Facultad De Ingeniería Universidad De Antioquia, (62), 83-90. Retrieved from https://revistas.udea.edu.co/index.php/ingenieria/article/view/12461