Jacobsen’s catalyst anchored on Al-MCM-41 and NH2 group modified Si-MCM-41 as heterogeneous enantioselective epoxidation catalyst using in situ generated dimethyldioxirane as oxidant


  • Jairo Cubillos Universidad de Antioquia
  • Wolfgang Hölderich RWTH Aachen University


Enantioselective epoxidation, Jacobsen’s catalyst, Immobilized catalyst, in situ generated DMD, catalyst degradation, recyclability


En este trabajo se investigó la actividad catalítica del catalizador de Jacobsen inmovilizado en Al-MCMC-41 y en NH2-Si-MCM-41 en la epoxidación enantioselectiva de tres olefinas proquirales, utilizando dimetildioxirano generado in situ como agente oxidante. Con este agente oxidante, el catalizador no sufrió cambios significativos en su estructura química. El catalizador se reutilizó exitosamente, cuando se inmovilizó por enlace químico covalente a través del ligando de salen.

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Author Biographies

Jairo Cubillos, Universidad de Antioquia

Departamento de Ingeniería Química

Wolfgang Hölderich, RWTH Aachen University

Department of Chemical Technology and Heterogeneous Catalysis


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How to Cite

Cubillos, J., & Hölderich, W. (2014). Jacobsen’s catalyst anchored on Al-MCM-41 and NH2 group modified Si-MCM-41 as heterogeneous enantioselective epoxidation catalyst using in situ generated dimethyldioxirane as oxidant. Revista Facultad De Ingeniería Universidad De Antioquia, (41), 31–47. Retrieved from https://revistas.udea.edu.co/index.php/ingenieria/article/view/19014