Catalizador de Jacobsen inmovilizado en Al-MCM-41 y en Si-MCM-41 modificada con grupos amino y su actividad en la epoxidación enantioselectiva heterogénea utilizando dimetildioxirano generado in situ como oxidante
DOI:
https://doi.org/10.17533/udea.redin.19014Palabras clave:
Epoxidación enantioselectiva, catalizador de Jacobsen, catalizador inmovilizado, DMD generado in situ, degradación del catalizador, reutilizaciónResumen
The enantioselective epoxidation of three prochiral olefins over Jacobsen’s catalyst immobilized on Al-MCM-41 and NH2-Si-MCM-41 in the presence of in situ generated DMD as the oxygen source was investigated. Experimental results indicate that the catalyst did not significantly suffer any change in its chemical structure. Therefore, the reusability of catalyst could be successfully achieved when it was immobilized by chemical bonding of the salen ligand.
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