Degradation and adsorption of AZO RR239 dye in aqueous solution by nanoscale zerovalent iron particles immobilized on sawdust
DOI:
https://doi.org/10.17533/udea.redin.14677Keywords:
zerovalent iron particles (ZVI), azo dye, sorption, kinetics, pseudo-second orderAbstract
Carra sawdust pretrated with formaldehyde was used to adsorb RR239 (reactive azo dye) at varying pH and zerovalent iron (ZVI) dosage. Modeling of kinetic results shows that sorption process is best described by the pseudo-second-order model. Batch experiments suggest that the decolorization efficiency was strongly enhanced with the presence of ZVI and low solution pH. The kinetics of dye sorption by mixed sorbent (5 g of sawdust and 180 mg of ZVI) at pH 2.0 was rapid, reaching more than 90% of the total discoloration in three minutes.
Downloads
References
H. Park, W. Choi. “Visible light and Fe (III)-mediated degradation of Acid Orange 7 in the absence of H2O2”. Journal of Photochemistry and Photobiology A: Chemistry. Vol. 159. 2003. pp. 241-247. DOI: https://doi.org/10.1016/S1010-6030(03)00141-2
J. Fan, Y. Guo, J. Wang, M. Fan. “Rapid decolourization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles”. Journal of Hazardous Materials. Vol. 166. 2009. pp. 904-910. DOI: https://doi.org/10.1016/j.jhazmat.2008.11.091
S. J. Allen, B. Koumanova. “Decolourisation of Water/ Wastewater Using Adsorption (Review)”. Journal of the University of Chemical Technology and Metallurgy. Vol. 40. 2005. pp. 175-192.
O. Hao, H. Kim, P. Chiang. “Decolorization of Wastewater. Critical Reviews”. Environmental Science and Technology. Vol. 30. 2000. pp. 449-505. DOI: https://doi.org/10.1080/10643380091184237
C. Martínez, E. Brillas. “Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: A general review”. Applied Catalysis B: Environmental. Vol. 87. 2009. pp. 105- 145. DOI: https://doi.org/10.1016/j.apcatb.2008.09.017
A. Adamu. Adsorptive Removal of Reactive Azo Dyes using Industrial Residue. M.Sc. Thesis. University of Addis Ababa. Ethiopia. Febrero de 2008. pp. 8-11.
K. Sohn , S. W. Kang , S. Ahn, M. Woo , S. Yang. “Fe (0) Nanoparticles for Nitrate Reduction: Stability, Reactivity, and Transformation”. Environ. Sci. Technol. Vol. 46. 2006. pp. 5514-5519. DOI: https://doi.org/10.1021/es0525758
G. Crini. “Non-conventional low-cost adsorbents for dye removal: A review”. Bioresource Technology. Vol. 97. 2006. pp. 1061-1085. DOI: https://doi.org/10.1016/j.biortech.2005.05.001
W. Epolito, H. Yang, L. Bottomley, S. Pavlostathis. “Kinetics of zero-valent iron reductive transformation of the anthraquinone dye Reactive Blue”. Journal of Hazardous Materials. Vol. 160. 2008. pp. 594-600. DOI: https://doi.org/10.1016/j.jhazmat.2008.03.033
W. Zhang. “Nanoscale iron particles for environmental remediation: An overview”. Journal of Nanoparticle Research. Vol. 5. 2003. pp. 323-332. DOI: https://doi.org/10.1023/A:1025520116015
O. Çelebi, Ç. Üzüm, T. Shahwan, H. N. Erten. “A radiotracer study of the adsorption behavior of aqueous Ba2+ ions on nanoparticles of zero-valent iron”. Journal of Hazardous Materials. Vol. 148. 2007. pp. 761-767. DOI: https://doi.org/10.1016/j.jhazmat.2007.06.122
B. Geng, Z. Jin , T. Li, X. Qi. “Kinetics of hexavalent chromium removal from water by chitosan-Feº nanoparticles”. Chemosphere. Vol. 75. 2009. pp. 825- 830. DOI: https://doi.org/10.1016/j.chemosphere.2009.01.009
H. Shu , M. Chang, H. Yu, W. Chen. “Reduction of an azo dye Acid Black 24 solution using synthesized nanoscale zerovalent iron particles”. Journal of Colloid and Interface Science. Vol. 314. 2007. pp. 89- 97. DOI: https://doi.org/10.1016/j.jcis.2007.04.071
Y. Lina, C. Weng, F. Chen. “Effective removal of AB24 dye by nano/micro-size zero-valent iron”. Separation and Purification Technology. Vol. 64. 2008. pp. 26-30. DOI: https://doi.org/10.1016/j.seppur.2008.08.012
H. Song, E. Carraway. “Catalytic hydrodechlorination of chlorinated ethenes by nanoscale zero-valent iron”. Applied Catalysis B: Environmental. Vol. 78. 2008. pp. 53-60. DOI: https://doi.org/10.1016/j.apcatb.2007.07.034
Y. Sun, X. Li , W. Zhang , H. Wang. “A method for the preparation of stable dispersion of zero-valent iron nanoparticles”. Colloids and Surfaces A: Physicochem and Eng. Aspects. Vol. 308. 2007. pp. 60-66. DOI: https://doi.org/10.1016/j.colsurfa.2007.05.029
W. Wang, Z. Jin , T. Li, H. Zhang, S. Gao. “Preparation of spherical iron nanoclusters in ethanol–water solution for nitrate removal”. Chemosphere. Vol. 65. 2006. pp. 1396-1404. DOI: https://doi.org/10.1016/j.chemosphere.2006.03.075
Y. Xu, D. Zhao. “Reductive immobilization of chromate in water and soil using stabilized iron nanoparticles”. Water research. Vol. 41. 2007. pp. 2101-2108. DOI: https://doi.org/10.1016/j.watres.2007.02.037
V. K. Garg, M. Amita, R. Kumar, R. Gupta. “Basic dye (methylene blue) removal from simulated wastewater by adsorption using Indian Rosewood sawdust: a timber industry waste”. Dyes and Pigments. Vol. 63. 2004. pp. 243-250. DOI: https://doi.org/10.1016/j.dyepig.2004.03.005
V. K. Garg, R. Kumar, R. Gupta. “Removal of malachite green dye from aqueous solution by adsorption using agro-industry waste: a case study of Prosopis cineraria”. Dyes and Pigments.Vol. 62. 2004. pp. 1-10. DOI: https://doi.org/10.1016/j.dyepig.2003.10.016
V. K. Garg, R. Gupta, A.B. Yadav, R. Kumar. “Dye removal from aqueous solution by adsorption on treated sawdust”. Bioresource Technology. Vol. 89. 2003. pp. 121-124. DOI: https://doi.org/10.1016/S0960-8524(03)00058-0
D. Karadag, M. Turan, E. Akgul, S.Tok, A. Faki. “Adsorption Equilibrium and Kinetics of Reactive Black 5 and Reactive Red 239 in Aqueous Solution onto Surfactant-Modified Zeolite”. Journal of Chemical and Engineering Data. Vol. 52. 2007. pp. 1615-1620 DOI: https://doi.org/10.1021/je7000057
I. Ghodbane, L. Nouri, O. Hamdaoui, M.Chiha. “Kinetic and equilibrium study for the sorption of cadmium (II) ions from aqueous phase by eucalyptus bark”. Journal of Hazardous Materials. Vol. 152. 2008. pp. 148-158. DOI: https://doi.org/10.1016/j.jhazmat.2007.06.079
A. A. Ahmad, B. H. Hameed, N. Aziz. “Adsorption of direct dye on palm ash:Kinetic and equilibrium modeling”. Journal of Hazardous Materials. Vol. 141. 2007. 70-76. DOI: https://doi.org/10.1016/j.jhazmat.2006.06.094
F. A. Batzias, D. K. Sidiras. “Simulation of dye adsorption by beech sawdust as affected by pH”. Journal of Hazardous Materials. Vol. 141. 2007. pp. 668-679. DOI: https://doi.org/10.1016/j.jhazmat.2006.07.033
A. Shukla, Y. Zhang , P. Dubey, J. L. Margrave , S.S. Shukla. “The role of sawdust in the removal of unwanted materials from water”. Journal of Hazardous Materials. Vol. 95. 2002. pp. 137-152. DOI: https://doi.org/10.1016/S0304-3894(02)00089-4
C. K. Lee, K. S. Low; S. W. Chow. “Chrome Sludge as an Adsorbent for Colour Removal”. Enviromental Technology. Vol. 17. 1996. pp. 1023-1028. DOI: https://doi.org/10.1080/09593331708616471
C. Namasivayam, D. Prabha, M. Kumutha. “Removal of direct red and acid brilliant blue by adsorption on to banana pith”. Bioresour. Technol. Vol. 64. 1998. pp. 77-79. DOI: https://doi.org/10.1016/S0960-8524(97)86722-3
P. B. Rai, S. S. Banerjee, R. V. Jayaram. “Removal of Disperse Dyes from Aqueous Solution Using Sawdust and BDTDA-Sawdust”. Journal of Dispersion Science and Technology. Vol. 28. 2007. pp. 1066-1071. DOI: https://doi.org/10.1080/01932690701524752
A. S. Özcan, A. Özcan. “Adsorption of acid dyes from aqueous solutions ontoacid-activated bentonita”. Journal of Colloid and Interface Science. Vol. 276. 2004. pp. 39-46 DOI: https://doi.org/10.1016/j.jcis.2004.03.043
P. Leechart, W. Nakbanpote, P. Thiravetyan. “Application of ‘waste’ wood-shaving bottom ash for adsorption of azo reactive dye”. Journal of Environmental Management. Vol. 90. 2009. pp. 912- 920. DOI: https://doi.org/10.1016/j.jenvman.2008.02.005
Ö. Tunc, H. Tanacı, Z. Aksu. “Potential use of cotton plant wastes for the removal of Remazol Black B reactive dye”. Journal of Hazardous Materials. Vol. 163. 2009. pp. 187-198. DOI: https://doi.org/10.1016/j.jhazmat.2008.06.078
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2018 Revista Facultad de Ingeniería
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Revista Facultad de Ingeniería, Universidad de Antioquia is licensed under the Creative Commons Attribution BY-NC-SA 4.0 license. https://creativecommons.org/licenses/by-nc-sa/4.0/deed.en
You are free to:
Share — copy and redistribute the material in any medium or format
Adapt — remix, transform, and build upon the material
Under the following terms:
Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
NonCommercial — You may not use the material for commercial purposes.
ShareAlike — If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.
The material published in the journal can be distributed, copied and exhibited by third parties if the respective credits are given to the journal. No commercial benefit can be obtained and derivative works must be under the same license terms as the original work.
Twitter