Macroporous hydroxyapatite obtained in the Universidad de Antioquia: synthesis, characterization and comparison with the spongy calcined bovine bone
DOI:
https://doi.org/10.17533/udea.redin.327318Keywords:
macroporous hydroxyapatite, characterization of materials, bioceramic, implants bonesAbstract
Macroporous blocks of hydroxyapatite were obtained and they were characterized by atomic absorption, x-rays diffraction, infrared and electronic microscopy SEM. The macroporosity was induced with three natural macroporous agents: montanoa quadrangularis, asparagus ofssicynali and zea may, An experimental design was used for hydroxyapatite synthesis with these agents. The macroporous blocks were compared with the spongy calcined bovine bone, the best results were obtained with the block elaborated with zea mays. The block presented the following characteristics: hardness in the Mohs scale of 2,5-3,0; total porosity by water absorption: 85% in volume; porosity by image analysis: 18,61% in area; maximum diameter of pore: 1.048 µm; modulus of rupture: 6,35 Kg/cm2 ; Ca/P relation: 1,65 and density: 3,11 g/cm3 .
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Vallet, María. “Biocerámicas: Inertes y bioactivas”. En: Revista de la Real Academia de Ciencias Exactas, Físi-cas y Naturales. Vol. 90. No. 4. 1996. pp. 269-273.
Sinha, M. K. et al. “Porous Hydroxiapatite ceramic and its clinical applications”. En: Interceram. Vol. 49. No. 2. Alemania. 2000. pp. 102-105.
Korkusuz, Feza. et al. “Do porous calcium hydroxiapatite ceramics cause porosis in bone? A bone densitometry and biomechanical study on cortical bones of rabbits”. En: Biomaterials. Vol. 16. No. 7. 1995. pp. 537-543.
Arita, I. H. et al. “Chemistry and sintering behaviour of thin hydroxyapatite ceramics with controlled porosity”. En: Biomaterials. Vol. 16. No. 5. pp. 403-408.
Echavarría, Alejandro et al. “HAP sintética de porosidad inducida-Comparación con el hueso calcinado”. En: Revista Facultad de Ingeniería. No. 19. Medellín. 1999. pp. 56-64.
Klein, C. et al. “Osseous substance formation induced in porous calcium phosphate ceramics in soft tissues”. En: Biomaterials. Vol. 15. No. 1. 1994. pp. 31-34.
Engin, N. Ozgur. Manufacture of hidroxiapatita bioceramics. Tesis M. Sc. –Middle East Technical University-Ankara (Turkey). 1999. p. 9. http://www.mete.metu.edu.tr/RESEARCH/PROJECTS/CERAMIC/pubmacro.htm
Gómez, J. y Clemente, R. “Técnicas de precipitación como alternativa a la tecnología de recubrimientos con HAP mediante plasma spray”. En: Revista Latinoamericana de Metalurgia y Materiales. Vol. 20. No. 1. 2000. pp. 30-38.
Piñeda, H. et al. Eliminación de fluoruros utilizando hidroxiapatita. XXVI Congreso Interamericano de Ingeniería Sanitaria y Ambiental. Córdoba. 1998. 13 p.
González, Ramón. “Biomateriales: Una ciencia moderna que exige una adecuada educación y formación profesional”. En: Revista Cubana Investigaciones Biomédicas. 13 (1-2). 1994. pp. 26-36.
Martínez-González et al. La hidroxiapatita en el relleno de los defectos óseos. Julio, 1997. http://www.coem.org/revista/anterior/07-97/articulo.htm
Restrepo, Gloria. Síntesis, caracterización y pro-piedades fisicoquímicas de óxidos mixtos TiO2-SiO2 y ZrO2-SiO2, eventualmente dopados con Fe(III). Tesis Ph.D. –Universidad de Sevilla- Sevilla (España). 1999.
Rouquerol, J. et al. “Recomendations for the characte-rization of porous solids”. En: Pure & Apllied Chemistry. Vol. 66(8). 1994.
Mari, Eduardo. Los materiales cerámicos: Procesos cerámicos. Buenos Aires. Editorial Alsina. 1998. pp. 85-90.
González, R. C. y R. E. Woods. Tratamiento de imágenes. Delaware. Addison-Wesley Iberoamericana S.A., 1996. p. 773.
Shi, D. and G. Jiang. “Synthesis of hidroxyapatite films on porous Al2O3 substrate for hard tissue prosthetics”. En: Materials Science and Engineering and Building. 1998. Elsevier. p. 8.
Rhee, S. H. “Synthesis of hydroxyapatite via mechanochemical treatmen”. En: Biomaterials. Vol. 23. 2002.
Park, J. and R. Lakes. Biomaterials. An Introduction. Plenum Press, Nueva York. 1992.
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