Epoxidación enantioselectiva de estireno usando dimetildioxirano generado in-situ y un complejo de base de schiff homoquiral dimérico de Mn(III) como catalizador

Autores/as

  • Brayan David Verdugo-Torres Universidad Pedagógica y Tecnológica de Colombia
  • Jairo Antonio Cubillos-Lobo Universidad Pedagógica y Tecnológica de Colombia
  • Hugo Alfonso Rojas-Sarmiento Universidad Pedagógica y Tecnológica de Colombia

DOI:

https://doi.org/10.17533/udea.redin.n89a10

Palabras clave:

epoxidación enantioselectiva, estireno, dimetildioxirano, catalizador dimérico, reutilización del catalizador

Resumen

Se ha explorado la epoxidación enantioselectiva de estireno utilizando dimetildioxirano (DMD) generado in-situ y un complejo de base de Schiff homoquiral dimérico de Mn (III). Los parámetros evaluados fueron la relación molar olefina/oxidante, la cantidad de catalizador, la temperatura de reacción y la presencia de co-catalizadores coordinadores de nitrógeno. Se obtuvieron conversiones por encima de 99% y excesos enantioméricos cercanos al 66%. La reacción fue completamente selectiva hacia el óxido de estireno usando 2% en moles de carga de catalizador, 1.36 mmol de KHSO5 en 8 ml de agua, ausencia de cocatalizador y 17ºC como temperatura de reacción. Además, el catalizador puede reutilizarse hasta tres veces con una leve disminución de la actividad catalítica debido principalmente, a la pérdida física del catalizador durante la etapa de recuperación del catalizador, y en menor medida a su degradación oxidativa.

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Biografía del autor/a

Brayan David Verdugo-Torres, Universidad Pedagógica y Tecnológica de Colombia

Grupo de Catálisis, Escuela de Ciencias Químicas.

Jairo Antonio Cubillos-Lobo, Universidad Pedagógica y Tecnológica de Colombia

Grupo de Catálisis, Escuela de Ciencias Químicas.

Hugo Alfonso Rojas-Sarmiento, Universidad Pedagógica y Tecnológica de Colombia

Grupo de Catálisis, Escuela de Ciencias Químicas.

Citas

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Publicado

2018-10-19

Cómo citar

Verdugo-Torres, B. D., Cubillos-Lobo, J. A., & Rojas-Sarmiento, H. A. (2018). Epoxidación enantioselectiva de estireno usando dimetildioxirano generado in-situ y un complejo de base de schiff homoquiral dimérico de Mn(III) como catalizador. Revista Facultad De Ingeniería Universidad De Antioquia, (89), 73–80. https://doi.org/10.17533/udea.redin.n89a10

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