Synthesis and characterization of functionalized mesostructured silicas with acid sulphonic groups
DOI:
https://doi.org/10.17533/udea.redin.14600Keywords:
co-condensation, grafting, mesoporous, functionalization, characterizationAbstract
Hexagonal (MCM-41, SBA-15, and HMS) and cubic (MCM-48) mesostructured silicas were synthesized and functionalized with the propylsulphonic acid group, by grafting and co-condensation methods. Structural conformation, physical-chemistry characterization, and morphology of the materials was performed by XRD, FT-IR, TGA, and SEM techniques. Higher functionalization degrees were reached by co-condensation method, for MCM-48 and SBA-15 mesophases. These higher functionalization degrees lead to less thermally and structurally stable materials than those obtained by the grafting method.
Downloads
References
K. S. W. Sing, D. H. Everett, R. A. W. Haul, L. Moscou, R. A. Pietotti, J. Rouquerol, T. Siemienieska. “Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity”. Pure Appl Chem. Vol. 57. 1985. pp. 603-619. DOI: https://doi.org/10.1351/pac198557040603
T. Yanagisawa, T. Shimizu, K. Kuroda, C. Kato. “The preparation of alkyltriinethylaininonium–kaneinite complexes and their conversion to microporous materials”. Bull. Chem. Soc. Jpn. Vol. 63. 1990. pp. 988- 992. DOI: https://doi.org/10.1246/bcsj.63.988
C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, J. S. Beck. “Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism”. Nature. Vol. 359. 1992. pp. 710-712. DOI: https://doi.org/10.1038/359710a0
J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T. W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins, J. L. Schlenkert. “A new family of mesoporous molecular sieves prepared with liquid crystal templates”. J. Am. Chem. Sot. Vol. 114. 1992. pp. 10834-10843. DOI: https://doi.org/10.1021/ja00053a020
L. L. Hench, J. K. West. “The Sol-Gel Process”. Chem. Rev. Vol. 90. 1990 pp. 33-72. DOI: https://doi.org/10.1021/cr00099a003
Q. Huo, D. I. Margolese, U. Ciesla, D. G. Demuth, P. Feng, T. E. Gier, P. Sieger, A. Firouzi, B. F. Chmelka. “organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays”. Chem. Mater. Vol. 6. 1994. pp. 1176-1191. DOI: https://doi.org/10.1021/cm00044a016
P. T. Tanev, T. J. Pinnavaia. “A neutral templating route to mesoporous molecular sieves”. Science. Vol. 267. 1995. pp. 865-867. DOI: https://doi.org/10.1126/science.267.5199.865
Y. Wei, D. Jin, T. Ding, W. H. Shih, X. Liu, S. Z. D. Cheng, Q. Fu. “A non-surfactant templating route to mesoporous silica materials”. Adv. Mater. Vol. 10. 1998. pp. 313-316. DOI: https://doi.org/10.1002/(SICI)1521-4095(199803)10:4<313::AID-ADMA313>3.0.CO;2-M
D. Margolese, J. A. Melero, S. C. Christiansen, B. F. Chmelka, G. D Stucky. “Direct syntheses of ordered SBA-15 mesoporous silica containing sulfonic acid groups”. Chem. Mater. Vol. 12. 2000. pp. 2448-2459. DOI: https://doi.org/10.1021/cm0010304
Y. Mori, T. J. Pinnavaia. “Optimizing Organic Funcionality in Mesoestructured Silica: Direct Assembly of Mercaptopropyl Groups in Wormhole Framework Structures”. Chem. Mater. Vol. 13. 2001. pp. 2173. DOI: https://doi.org/10.1021/cm010048r
S. L. Burkett, S. D. Sims, S. Mann. “Synthesis of hybrid inorganic–organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors”. Chem. Commun. Vol. 11. 1996. pp. 1367-1368. DOI: https://doi.org/10.1039/CC9960001367
A. Stein, B. J. Melde, R. C. Schroden. “Hybrid inorganic-organic mesoporous silicates-nanoscopic reactors coming of age”. Adv. Mater. Vol. 12. 2000. pp. 1403-1419. DOI: https://doi.org/10.1002/1521-4095(200010)12:19<1403::AID-ADMA1403>3.0.CO;2-X
Y. Wei, Q. Feng, J. Xu, H. Dong, K. Qiu, S. Jansen, R. Yin, K. Ong. “Polymethacrylate-silica hybrid nanoporous materials: a bridge between inorganic and polymeric molecular sieves”. Adv. Mater. Vol. 12. 2000. pp. 1448-1450. DOI: https://doi.org/10.1002/1521-4095(200010)12:19<1448::AID-ADMA1448>3.0.CO;2-W
X. Feng, G. E. Fryxell, L. Wang, Y. A. Kim, J. Liu, K. M. Kemner. “Functionalized monolayers on ordered mesoporous supports”. Science. Vol. 276. 1997. pp. 923-926. DOI: https://doi.org/10.1126/science.276.5314.923
Q. Huo, D. I. Margolese, G. D. Stucky. “surfactant control of phases in the synthesis of mesoporous silicabased materials”. Chem. Mater. Vol. 8. 1996. pp. 1147- 1160. DOI: https://doi.org/10.1021/cm960137h
J. A. Melero, R.V. Grieken, G. Morales. “Advances in the synthesis and catalytic applications of organosulfonic-functionalized mesostructured materials”. Chem. Rev. Vol. 106. 2006. pp. 3790-3812. DOI: https://doi.org/10.1021/cr050994h
J. A. Posada. Aumento de la resistencia térmica de una estructura acidosulfónica para la obtención de acetato de n-butilo por destilación reactiva. Tesis de Maestría en Ingeniería-Ingeniería Química. Universidad Nacional de Colombia sede Manizales. 2008. pp. 1- 174.
I. Díaz, F. Mohíno, J. Pérez Pariente, E. Sastre. “Synthesis of MCM-41 materials functionalised with dialkylsilane groups and their catalytic activity in the esterifi cation of glycerol with fatty acids”. Appl. Catal., A. Vol. 242. 2003. pp. 161-169. DOI: https://doi.org/10.1016/S0926-860X(02)00501-X
I. Díaz, F. Mohíno, T. Blasco, E. Sastre, J. Pérez- Pariente. “Infl uence of the alkyl chain length of HSO3- R-MCM-41 on the esterifi cation of glycerol with fatty acids”. Microporous Mesoporous Mater. Vol. 80. 2005. pp. 33- 42. DOI: https://doi.org/10.1016/j.micromeso.2004.11.011
M. H. Lim, C. F. Branford, A. Stein. “Synthesis of ordered microporous silicates with organosulfur surface groups and their applications as solid acid catalysts”. Chem. Mater. Vol. 10. 1998. pp. 467- 470. DOI: https://doi.org/10.1021/cm970713p
I. Díaz, C. Márquez Álvarez, F. Mohíno, J. Pérez- Pariente, E. Sastre. “combined alkyl and sulfonic acid functionalization of mcm-41-type silica: Part 2. Esterifi cation of glycerol with fatty acids”. J. Catal. Vol. 193. 2000. pp. 295-302. DOI: https://doi.org/10.1006/jcat.2000.2899
G. Busca. “The use of vibrational spectroscopies in studies of heterogeneous catalysis by metal oxides: an introduction”. Catal. Today. Vol. 27. 1996. pp. 323-352. DOI: https://doi.org/10.1016/0920-5861(96)88647-0
H. Dung. Organic-Inorganic hybrid mesoporous sílica, materials and their application as a host matrix for protein molecules. Drexel University. Thesis: Doctor of Philosophy. 2002. pp. 291.
X. Wang, S. Cheng, J. C. C. Chan, J. C. H. Chao. “Template-free synthesis of mesoporous phenylsulfonic
acid functionalized silica”. Microporous Mesoporous Mater. Vol. 96. 2006. pp. 321-330. DOI: https://doi.org/10.1016/j.micromeso.2006.07.023
X. Wang, S. Cheng, J. C. C. Chan. “Propylsulfonic acid-functionalized mesoporous silica synthesized by in situ oxidation of thiol groups under template-free condition”. J. Phys. Chem. C. Vol. 111. 2007. pp. 2156-2164. DOI: https://doi.org/10.1021/jp066924b
S. Hamoudi, S. Royer, S. Kaliaguine. “Propyland arene-sulfonic acid functionalized periodic mesoporous organosilicas”. Microporous Mesoporous Mater. Vol. 71. 2004. pp. 17-25. DOI: https://doi.org/10.1016/j.micromeso.2004.03.009
I. Díaz, F. Mohíno, J. Pérez Pariente, E. Sastre. “Study by TG–MS of the oxidation of SH-MCM-41 to SO3HMCM- 41”. Thermochim. Acta. Vol. 413. 2004. pp. 201-207. DOI: https://doi.org/10.1016/j.tca.2003.10.008
D. Das, J. F. Lee, S. Cheng. “Selective synthesis of Bisphenol-A over mesoporous MCM silica catalysts functionalized with sulfonic acid groups”. J. Catal. Vol. 223. 2004. pp. 152-160. DOI: https://doi.org/10.1016/j.jcat.2004.01.025
Y. Shao, L. Wang, J. Zhang, M. Anpo. “Synthesis and characterization of high hydrothermally stable Cr- MCM-48”. Microporous Mesoporous Mater. Vol. 109. 2008. pp. 271-277. DOI: https://doi.org/10.1016/j.micromeso.2007.05.001
H. Ji, Y. Fan, W. Jin, C. Chen, N. Xu. “Synthesis of Si-MCM-48 membrane by solvent extraction of the surfactant template” J. Non-Cryst. Solids. Vol. 354 2008. pp. 2010-2016. DOI: https://doi.org/10.1016/j.jnoncrysol.2007.11.011
Y. Sakamoto, I. Díaz, O. Terasaki, D. Zhao, J. Pérez Pariente, J. M. Kim, G. D. Stucky. “Three-dimensional cubic mesoporous structures of SBA-12 and related materials by electron crystallography”. J. Phys. Chem. B. Vol. 106. 2002. pp. 3118-3123. DOI: https://doi.org/10.1021/jp014094q
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2018 Revista Facultad de Ingeniería
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Revista Facultad de Ingeniería, Universidad de Antioquia is licensed under the Creative Commons Attribution BY-NC-SA 4.0 license. https://creativecommons.org/licenses/by-nc-sa/4.0/deed.en
You are free to:
Share — copy and redistribute the material in any medium or format
Adapt — remix, transform, and build upon the material
Under the following terms:
Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
NonCommercial — You may not use the material for commercial purposes.
ShareAlike — If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.
The material published in the journal can be distributed, copied and exhibited by third parties if the respective credits are given to the journal. No commercial benefit can be obtained and derivative works must be under the same license terms as the original work.
Twitter