Heat flow modeling in the alkaline activation process of fly ash
DOI:
https://doi.org/10.17533/udea.redin.20230624Keywords:
Fly ash, alkaline cement, descriptive modelAbstract
Cement production plays an important role in strengthening the infrastructure of growing countries such as Colombia. However, the production of this material has a high energy cost and contributes to the emission of large amounts of CO2. To address these environmental concerns, it is essential to explore alternative materials that can partially or completely replace traditional cement. Alkaline activated cement (AAC) has emerged as a promising candidate in this regard. Due to this, it is necessary to understand the process of alkaline activation and the variables that influence it. This research proposes a phenomenological-based semi-physical model, which predicts the performance of some variables that control alkaline activation: activator concentration (NaOH), heat flow, and degree of reaction. The model results show that with the increment of the activator concentration, the degree of reaction also increases. Furthermore, the model has an accurate response compared with the Freisleben-Hansen model. The integral square error criterion (ISE) was used in this comparison.
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M. M. A. Elahi, M. M. Hossain, M. R. Karim, M. F. Mohd-Zain, and C. Shearer, “A review on alkali-activated binders: Materials composition and fresh properties of concrete,” Construction and Building Materials, vol. 210, Nov. 10, 2020. [Online]. Available: https://doi.org/10.1016/j.conbuildmat.2020.119788
A. Palomo, O. Maltseva, I. Garcia-Lodeiro, and A. Fernández-Jiménez, “Portland versus alkaline cement: Continuity or clean break: “a key decision for global sustainability”,” Sec. Solid State Chemistry, vol. 9, Oct. 11 2021. [Online]. Available: https://doi.org/10.3389/fchem.2021.705475
A. A. Hoyos-Montilla, F. Puertas, and J. I. Tobón, “Microcalorimetric study of the effect of calcium hydroxide and temperature on the alkaline activation of coal fly ash,” Journal of Thermal Analysis and Calorimetry, vol. 131, Sep. 13 2017. [Online]. Available: https://doi.org/10.1007/s10973-017-6715-4
P. Zhang, Z. Gao, J. Wang, J. Guo, S. Hu, and Y. Ling, “Properties of fresh and hardened fly ash/slag based geopolymer concrete: A review,” Journal of Cleaner Production, vol. 270, May. 20, 2020. [Online]. Available: https://doi.org/10.1016/j.jclepro.2020.122389
F. Xie, Z. Liu, D. Zhang, J. Wang, T. Huang, and D. Wang, “Reaction kinetics and kinetics models of alkali activated phosphorus slag,” Construction and Building Materials, vol. 237, Nov. 26, 2019. [Online]. Available: https://doi.org/10.1016/j.conbuildmat.2019.117728
P. Termkhajornkit and R. Barbarulo, “Modeling the coupled effects of temperature and fineness of portland cement on the hydration kinetics in cement paste,” Cement and Concrete Research, vol. 42, no. 3, Nov. 22, 2011. [Online]. Available: https://doi.org/10.1016/j.cemconres.2011.11.016
K. Bong-Park, T. Noguchi, and J. Plawsky, “Modeling of hydration reactions using neural networks to predict the average properties of cement paste,” Cement and Concrete Research, vol. 35, no. 9, Aug. 02, 2004. [Online]. Available: https://doi.org/10.1016/j.cemconres.2004.08.004
A. A. Siyal, K. Azizi-Azizli, Z. Man, L. Ismail, and M. Irfan-Khan, “Geopolymerization kinetics of fly ash based geopolymers using jmak model,” Ceramics International, vol. 42, no. 14, Jul. 01, 2016. [Online]. Available: https://doi.org/10.1016/j.ceramint.2016.07.006
R. Xiao, X. Jiang, M. Zhang, P. Polaczyk, and B. Huang, “Analytical investigation of phase assemblages of alkali-activated materials in cao-sio2-al2o3 systems: The management of reaction products and designing of precursors,” Materials & Design, vol. 194, Jul. 20, 2020. [Online]. Available: https://doi.org/10.1016/j.matdes.2020.108975
Y. Sun and H. S. L. K. Q Wang and, “Prediction of compressive strength development for blended cement mortar considering fly ash fineness and replacement ratio,” Construction and Building Materials, vol. 271, Oct. 20, 2020. [Online]. Available: https://doi.org/10.1016/j.conbuildmat.2020.121532
X. Y. Wang and H. S. Lee, “Modeling the hydration of concrete incorporating fly ash or slag,” Cement and Concrete Research, vol. 40, no. 7, Mar. 01, 2010. [Online]. Available: https://doi.org/10.1016/j.cemconres.2010.03.001
L. Y. Xu, Y. Alrefaei, Y. S. Wang, and J. G. Dai, “Recent advances in molecular dynamics simulation of the n-a-s-h geopolymer system: modeling, structural analysis, and dynamics,” Construction and Building Materials, vol. 276, Dec. 24, 2020. [Online]. Available: https://doi.org/10.1016/j.conbuildmat.2020.122196
I. García-Lodeiro, S. Donatello, A. Fernandez-Jiménez, and A. Palomo, “Ehydration of hybrid alkaline cement containing a very large proportion of fly ash: A descriptive model,” Materials, vol. 9, no. 605, Jul. 18, 2016. [Online]. Available: https://doi.org/10.3390/ma9070605
J. J. Thomas, J. J. Biernacki, J. W. Bullard, S. Bishnoi, J. S. Dolado, G. W. Scherer, and et al., “Modeling and simulation of cement hydration kinetics and microstructure development,” Cement and Concrete Research, vol. 41, no. 12, Oct. 07, 2010. [Online]. Available: https://doi.org/10.1016/j.cemconres.2010.10.004
D. Marchon and R. Flatt, “8 - mechanisms of cement hydration,” Science and Technology of Concrete Admixtures, vol. 131, Nov. 20 2015. [Online]. Available: https://doi.org/10.1016/B978-0-08-100693-1.00008-4
B. Sun, G. Ye, and G. de Schutter, “A review: Reaction mechanism and strength of slag and fly ash-based alkali-activated materials,” Construction and Building Materials, vol. 326, Feb. 02, 2022. [Online]. Available: https://doi.org/10.1016/j.conbuildmat.2022.126843
T. M. Works. (1994-2023) Elegir un solver de ode. [Online]. Available: https://es.mathworks.com/help/matlab/math/choose-an-ode-solver.html
G. M. Idorn and N. Thaulow, “Effectiveness of research on fly ash in concrete,” Cement and Concrete Research, vol. 15, no. 3, Dec. 21, 1984. [Online]. Available: https://doi.org/10.1016/j.conbuildmat.2020.119788
M. Letizia-Guerra, L. Sorini, and L. Stefanini, “Quantile and expectile smoothing based on l1-norm and l2-norm fuzzy transforms,” International Journal of Approximate Reasoning, vol. 107, Jan. 23, 2019. [Online]. Available: https://doi.org/10.1016/j.ijar.2019.01.011
J. M. Pommersheim and J. R. Clifton, “Mathematical modeling of tricalcium silicate hydration,” Cement and Concrete Research, vol. 9, no. 6, Sep. 11, 1979. [Online]. Available: https://doi.org/10.1016/0008-8846(79)90072-3
A. A. Hoyos-Montilla, F. Puertas, and J. I. Tobón, “No accessstudy of the reaction stages of alkali-activated cementitious materials using microcalorimetry,” Advances in Cement Research, vol. 33, no. 1, Jan. 22 2021. [Online]. Available: https://doi.org/10.1680/jadcr.19.00025
M. Narmluk and T. Nawa, “Effect of fly ash on the kinetics of portland cement hydration at different curing temperatures,” Cement and Concrete Research, vol. 41, no. 6, Feb. 24 2011. [Online]. Available: https://doi.org/10.1016/j.cemconres.2011.02.005
Z. Li, G. Xu, and X. Shi, “Reactivity of coal fly ash used in cementitious binder systems: A state-of-the-art overview,” Fuel, vol. 301, May. 08 2021. [Online]. Available: https://doi.org/10.1016/j.fuel.2021.121031
O. Heinz and H. Heinz, “Cement interfaces: Current understanding, challenges, and opportunities,” Langmuir, vol. 37, no. 21, May. 17 2021. [Online]. Available: https://doi.org/10.1021/acs.langmuir.1c00617
H. Wang, X. Zhao, T. Wang, L. Su, B. Zhou, and Y. Li, “Determination of gel products in alkali-activated fly ash-based composites incorporating inorganic calcium additives,” Advances in Materials Science and Engineering, vol. 2022, Feb. 15, 2022. [Online]. Available: https://doi.org/10.1155/2022/7476671
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